Journal article
Syntheses and structure of bis(pentamethylcyclopentadienyl)dithiophosphinato complexes.



Publication Details
Authors:
Ebels, J.; Pietschnig, R.; Nieger, M.; Niecke, E.; Kotila, S.
Publisher:
John Wiley & Sons, Inc.DO - 10.1002/(SICI)1098-1071(1997)8:6<521::AID-HC11>3.0.CO;2-T
Publication year:
1997
Journal:
Heteroatom Chemistry
Pages range:
521-525
Volume number:
8
Start page:
521
End page:
525
ISSN:
1042-7163

Abstract
Bis(pentamethylcyclopentadienyl)phosphine Cp*2PH reacts with S under basic conditions to give the corresponding dithiophosphinate salts M+ Cp*2PS2- (5 M+ = HNEt3+, 6 M+ = Li+), which are formed via the intermediate Cp*2P(S)H (Cp* = C5Me5) (4). Both salts on treatment with Co (II) chloride give rise to the transition metal dithiophosphinate I. The structures of 5, 6 and I were detd. by x-ray crystallog. [on SciFinder(R)]


Keywords
cobalt biscyclopentadienyl dithiophosphinate prepn crystal structure, crystal structure biscyclopentadienyl dithiophosphinate cobalt, dithiophosphinate biscyclopentadienyl prepn cobalt crystal structure, mol structure biscyclopentadienyl dithiophosphinate cobalt


Authors/Editors

Last updated on 2019-25-07 at 16:03