Journal article
P-C bond formation via P-H addition of a fluoroaryl phosphinic acid to ketones.



Publication Details
Authors:
Orthaber, A.; Albering, J.; Belaj, F.; Pietschnig, R.
Publisher:
Elsevier B.V.DO - 10.1016/j.jfluchem.2010.07.008
Publication year:
2010
Journal:
Journal of Fluorine Chemistry
Pages range:
1025-1031
Volume number:
131
Start page:
1025
End page:
1031
ISSN:
0022-1139

Abstract
The synthesis, structure and reactivity of the fluoroaryl phosphinic acid HF4C6-P(O)H(OH) is reported and compared to a sterically comparable yet non-fluorinated analog with similar size. The fluoroaryl phosphinic acid undergoes reversible P-H addn. to the carbonyl functionality of ketones under formation of a P-C bond which is retained in the resulting α-hydroxy phosphinic acid. The latter shows an extended 2D hydrogen bonded network in the solid state. [on SciFinder(R)]


Keywords
crystal structure fluoroaryl phosphinic acid prepn, fluoroaryl phosphinic acid reversible addn ketone, mol structure optimized fluoroaryl phosphinic acid, tautomerization fluoroaryl phosphinic acid DFT study


Authors/Editors

Last updated on 2019-25-07 at 16:01