Journal article
Ferrocenyldihalophosphines.
Publication Details
Authors: | Pietschnig, R.; Niecke, E.
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Journal: | Bulletin de la Societe Chimique de France |
Abstract
An improved synthesis for ferrocenyldichlorophosphine, FcPCl2 (Fc = C5H4FeC5H5) is reported. The availability of this compd. gives access to the other, previously unknown members of the homologous ferrocenyldihalophosphine series, FcPX2 (X = F, Br, I). The latter are characterized by NMR and high-resoln. mass spectroscopy. The class of ferrocenyldihalophosphines is a valuable synthon for the generation of a large variety of ferrocenylphosphines. [on SciFinder(R)]
Keywords
ferrocenyldihalophosphine prepn, phosphine ferrocenyl dihalo prepn