Aufsatz in einer Fachzeitschrift
Phosphoryl Triamide Polymers Revisited: Identification of Structural Units with ESI-MS/MS and Solid State NMR.



Details zur Publikation
Autor(inn)en:
Pietschnig, R.; Fechtelkord, M.; Spirk, S.; Rechberger, G.
Verlag:
SpringerDO - 10.1007/s10904-007-9168-6
Publikationsjahr:
2008
Zeitschrift:
Journal of Inorganic and Organometallic Polymers and Materials
Seitenbereich:
272-276
Jahrgang/Band:
18
Erste Seite:
272
Letzte Seite:
276
ISSN:
1574-1443

Zusammenfassung, Abstract
The thermal condensation of phosphoryl triamide was reinvestigated and analyzed with ESI-MS as well as 31P- and 1H-NMR spectroscopy in the solid state and in soln. Our results indicate that strongly crosslinked polymers are formed even at temps. lower than 300°; and, furthermore, evidence for facile partial hydrolysis of oligomeric condensation products on contact with water has been established using ESI-MS/MS. [on SciFinder(R)]


Schlagwörter
linear polymer phosphoryl triamide prepn


Autor(inn)en / Herausgeber(innen)

Zuletzt aktualisiert 2019-25-07 um 16:02