Journal article
Bis-3Ferrocenophanes with Central E-E'< Bonds (E, E'=P, SiH): Preparation, Properties, and Thermal Activation



Publication Details
Authors:
Isenberg, S.; Weller, S.; Kargin, D.; Valić, S.; Schwederski, B.; Kelemen, Z.; Bruhn, C.; Krekić, K.; Maurer, M.; Feil, C.; Nieger, M.; Gudat, D.; Nyulászi, L.; Pietschnig, R.
Publication year:
2019
Journal:
ChemistryOpen
Pages range:
1235-1243
Volume number:
8
Issue number:
10
ISSN:
2191-1363

Abstract
A series of bis-[3]ferrocenophanes of the general type Fe(C5H4E')2E-E(E'C5H4)2Fe (E=P, SiH and E'=PtBu, NneoPentyl, NSi(CH3)3) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X-ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.

Last updated on 2020-17-02 at 10:25