Aufsatz in einer Fachzeitschrift
Revealing the origin of magnetoresistance in unipolar amorphous organic field-effect transistors



Details zur Publikation
Autor(inn)en:
Saragi, T.; Isenberg, C.
Publikationsjahr:
2014
Zeitschrift:
Journal of Materials Chemistry C
Seitenbereich:
8569-8577
Abkürzung der Fachzeitschrift:
J. Mater. Chem. C
Jahrgang/Band:
2014
ISSN:
2050-7526

Zusammenfassung, Abstract
We report on the magnetoresistance (MR) effect in a unipolar p-channel field-effect transistor based on amorphous thin film of low molecular weight 2,2′,7,7′-tetrakis(diphenylamino)-9,9′-spirobifluorene (Spiro-TAD). To scrutinize the origin of this effect two themes have been studied: (i) the influence of gate dielectric SiO2 surface treatment and (ii) the importance of organic molecular p-dopant 1,3,4,5,7,8-hexafluorotetracyanonaphthoquinodimethane (F6-TNAP) thin films sandwiched between SiO2 and Spiro-TAD. A device fabricated on bare SiO2 shows larger MR than one fabricated on hexamethyldisilazane-treated SiO2, suggesting the bipolaron species as the origin of this effect. This could be understood through two aspects. (i) The stabilization of bipolaron, i.e. trapped charge-stabilized bipolaron. Due to large energy cost for bipolaron formation, the stabilization of bipolaron by a trap with opposite sign is favored. Additionally, interface doping of Spiro-TAD with F6-TNAP reveals a significant enhancement in MR caused by an increase in trap density and charge carriers, boosting the effectiveness of bipolaron stabilization. (ii) Larger energetic disorder that might compensate the energy cost for bipolaron formation is expected to be obtained for a device fabricated on bare SiO2 caused by dipolar disorder at the corresponding interface. Adding a thin layer of F6-TNAP is expected to increase the energetic disorder as well.


Schlagwörter
Organic Field-Effect Transistors, Organic Magnetoresistance, Organic Spintronics


Autor(inn)en / Herausgeber(innen)

Zuletzt aktualisiert 2019-01-11 um 16:05