Journal article
Direct reduction of iron ore pellets by H-2 and CO: In-situ investigation of the structural transformation and reduction progression caused by atmosphere and temperature
Publication Details
Authors: | Scharm, C.; Küster, F.; Laabs, M.; Huang, Q.; Volkova, O.; Reinmoeller, M.; Guhl, S.; Meyer, B. |
Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
Publication year: | 2022 |
Journal: | Minerals Engineering |
Pages range : | 107459 |
Volume number: | 180 |
Number of pages: | 15 |
ISSN: | 0892-6875 |
eISSN: | 1872-9444 |
DOI-Link der Erstveröffentlichung: |
Abstract
With the aim of reducing CO2 emissions in basic industries, the sector of iron and steel metallurgy is also faced with the question of how carbon can be replaced in ore reduction. By means of in-situ observation, this study investigates the direct reduction (DR) of individual iron ore pellets under an atmosphere of hydrogen (H-2) and carbon monoxide (CO) and at temperatures between 800 degrees C and 1100 degrees C at atmospheric pressure. The progress of the reduction, i.e. the phase change and the structural change, is analysed by X-ray diffraction (XRD) and scanning electron microscopy equipped with energy-dispersive X-rays (SEM-EDX). To evaluate the porosities of the pellets, analytical porosimetry is compared to optical porosimetry findings obtained by analysing images of sections in the SEM (hereinafter called SEM porosimetry). Furthermore, the swelling behaviour is evaluated by video analysis and the reduction swelling index (RSI) is determined. The results show a higher reduction progress and a higher RSI under H-2 atmosphere than under CO atmosphere. Higher temperatures lead to faster reduction progress and to significant changes in the structural composition of the reduced pellets.
With the aim of reducing CO2 emissions in basic industries, the sector of iron and steel metallurgy is also faced with the question of how carbon can be replaced in ore reduction. By means of in-situ observation, this study investigates the direct reduction (DR) of individual iron ore pellets under an atmosphere of hydrogen (H-2) and carbon monoxide (CO) and at temperatures between 800 degrees C and 1100 degrees C at atmospheric pressure. The progress of the reduction, i.e. the phase change and the structural change, is analysed by X-ray diffraction (XRD) and scanning electron microscopy equipped with energy-dispersive X-rays (SEM-EDX). To evaluate the porosities of the pellets, analytical porosimetry is compared to optical porosimetry findings obtained by analysing images of sections in the SEM (hereinafter called SEM porosimetry). Furthermore, the swelling behaviour is evaluated by video analysis and the reduction swelling index (RSI) is determined. The results show a higher reduction progress and a higher RSI under H-2 atmosphere than under CO atmosphere. Higher temperatures lead to faster reduction progress and to significant changes in the structural composition of the reduced pellets.
Keywords
Carbon monoxide (CO), Direct reduction (DR), Hydrogen (H-2), Iron ore pellets, Mineral phase change, Reduction rate, Reduction swelling index (RSI), Structure analysis
