Aufsatz in einer Fachzeitschrift
Directing protonation in [FeFe] hydrogenase active site models by modifications in their second coordination sphere
Details zur Publikation
Autor(inn)en: | Ezzaher, S.; Gogoll, A.; Bruhn, C.; Ott, S. |
Publikationsjahr: | 2010 |
Zeitschrift: | Chemical Communications |
Seitenbereich: | 5775-5777 |
Jahrgang/Band : | 46 |
Erste Seite: | 5775 |
Letzte Seite: | 5777 |
ISSN: | 1359-7345 |
Zusammenfassung, Abstract
Subtle changes in the second coordination sphere of [Cl(2)bdtFe(2)-(CO)(4)(Ph2P-CH2-X-CH2-PPh2)] (bdt = benzene-1,2-dithiolate, X = NCH3, NCH2CF3, CH2) that do not influence the electronic character of the Fe-2 center can however direct protonation to three different sites: the N in the bis-phosphane, the Fe-Fe bond or the bdt-S.
Subtle changes in the second coordination sphere of [Cl(2)bdtFe(2)-(CO)(4)(Ph2P-CH2-X-CH2-PPh2)] (bdt = benzene-1,2-dithiolate, X = NCH3, NCH2CF3, CH2) that do not influence the electronic character of the Fe-2 center can however direct protonation to three different sites: the N in the bis-phosphane, the Fe-Fe bond or the bdt-S.
