Journal article
Transition probabilities from the ground state of the npπ ¹Π⁻u states of H₂
Publication Details
Authors: | Glass-Maujean, M.; Klumpp, S.; Werner, L.; Ehresmann, A.; Schmoranzer, H. |
Publication year: | 2007 |
Journal: | Molecular Physics |
Pages range : | 1535-1542 |
Volume number: | 105 |
Issue number: | 11-12 |
ISSN: | 0026-8976 |
eISSN: | 1362-3028 |
DOI-Link der Erstveröffentlichung: |
URN / URL: |
Abstract
The position and the intensities of the Q lines of the absorption spectrum of H2 were studied in the 81-72 nm wavelength range, using synchrotron light. The transition probabilities of the npπ 1Π-u v, J - X1Σ+g v'' = 0, J'' = J = 1 transitions with 3 ≤ n ≤ 12 have been measured and compared to calculated values. A good agreement has been found. The main discrepancies observed may well be related to local non-adiabatic couplings not included in the calculations. Vibrational couplings between levels with large Δv values up to Δv = 5 were observed affecting the transition probabilities.
The position and the intensities of the Q lines of the absorption spectrum of H2 were studied in the 81-72 nm wavelength range, using synchrotron light. The transition probabilities of the npπ 1Π-u v, J - X1Σ+g v'' = 0, J'' = J = 1 transitions with 3 ≤ n ≤ 12 have been measured and compared to calculated values. A good agreement has been found. The main discrepancies observed may well be related to local non-adiabatic couplings not included in the calculations. Vibrational couplings between levels with large Δv values up to Δv = 5 were observed affecting the transition probabilities.
