Journal article
Phosphorus-Rich Ferrocenophanes.
Publication Details
Authors: | Moser, C.; Belaj, F.; Pietschnig, R. |
Publisher: | Taylor & Francis Ltd. |
Publication year: | 2015 |
Journal: | Phosphorus, Sulfur, and Silicon and the Related Elements |
Pages range : | 837-844 |
Volume number: | 190 |
Start page: | 837 |
End page: | 844 |
ISSN: | 1026-7719 |
eISSN: | 1563-5325 |
DOI-Link der Erstveröffentlichung: |
Abstract
Some novel P-rich [3]ferrocenophanes are reported with PPP or NPN bridge. The P-bridged ferrocenophanes were obtained from the corresponding diphosphenes by intramol. thermal 2+2 addn. The reactivity of the diphosphenes toward hydrochlorination is explored as well. The NPN ferrocenophane is was obtained via salt metathesis and is one of the rare examples of this compd. class. Besides spectroscopic characterization, its structure was elucidated with x-ray crystallog. [on SciFinder(R)]
Some novel P-rich [3]ferrocenophanes are reported with PPP or NPN bridge. The P-bridged ferrocenophanes were obtained from the corresponding diphosphenes by intramol. thermal 2+2 addn. The reactivity of the diphosphenes toward hydrochlorination is explored as well. The NPN ferrocenophane is was obtained via salt metathesis and is one of the rare examples of this compd. class. Besides spectroscopic characterization, its structure was elucidated with x-ray crystallog. [on SciFinder(R)]
Keywords
ferrocenediamide cyclocondensation chlorophosphine, ferrocene diphosphene cycloaddn, mol structure phosphorus rich bridging ferrocenophane, phosphorus rich bridging ferrocenophane prepn crystal structure
