Aufsatz in einer Fachzeitschrift
Theoretical investigations on the 3d⁹4p - 3d¹⁰ spectrum of Cu II
Details zur Publikation
Autor(inn)en: | Dong, C.; Fritzsche, S.; Fricke, B. |
Publikationsjahr: | 2001 |
Zeitschrift: | Journal of Electron Spectroscopy and Related Phenomena |
Seitenbereich: | 157-161 |
Jahrgang/Band : | 114-116 |
ISSN: | 0368-2048 |
Zusammenfassung, Abstract
The low-lying lever structure and the 3d(9)4p - 3d(10) resonance and intercombination transitions of the spectrum CuII have been studied by using large-scale multiconfiguration Dirac-Fock wavefunctions. Excitation energies and transition probabilities are calculated by including all dominant effects of relativity, correlation, and of the rearrangement of the electron density within the same framework. Comparison with experiment and previous computations is made which shows a remarkable improvement in the accuracy of the theoretical results. (C) 2001 Elsevier Science B.V. All rights reserved.
The low-lying lever structure and the 3d(9)4p - 3d(10) resonance and intercombination transitions of the spectrum CuII have been studied by using large-scale multiconfiguration Dirac-Fock wavefunctions. Excitation energies and transition probabilities are calculated by including all dominant effects of relativity, correlation, and of the rearrangement of the electron density within the same framework. Comparison with experiment and previous computations is made which shows a remarkable improvement in the accuracy of the theoretical results. (C) 2001 Elsevier Science B.V. All rights reserved.
