Journal article
Concentration and Distribution Patterns of Perfluoroalkyl Acids in Sewage Sludge and in Biowaste in Hesse, Germany
Publication Details
Authors: | Stahl, T.; Gaßmann, M.; Falk, S.; Brunn, H. |
Publication year: | 2018 |
Journal: | Journal of Agricultural and Food Chemistry |
Pages range : | 10147–10153 |
Volume number: | 66 |
Issue number: | 39 |
ISSN: | 0021-8561 |
DOI-Link der Erstveröffentlichung: |
Abstract
A total of 201 sewage sludge and 45 biowaste samples were examined for 14 different perfluoroalkyl acids (PFAA). For perfluorooctanesulfonic acid, maximum concentrations of 698 μg/kg dry weight were measured in sewage sludge and for perfluorohexanesulfonic acid 29.0 μg/kg dry weight were found in biowaste. Looking at the fingerprints of both these matrixes it can be see that long-chain PFAA make up 85.9% of the total concentration in sewage sludge whereas short-chain PFAA only account for 14.1%. In contrast, the trend in biowaste is just the opposite, with 53.2% long-chain and 46.8% short-chain PFAA. These results lead to the conclusion that sewage sludge functions as a sink for long-chain PFAA, and the plants preferentially take up short-chain PFAA from the sludge/soil, as seen by the concentrations found in biowaste. It can be calculated that the total yearly amount of PFAA spread onto agricultural lands amount to 15.3 kg.
A total of 201 sewage sludge and 45 biowaste samples were examined for 14 different perfluoroalkyl acids (PFAA). For perfluorooctanesulfonic acid, maximum concentrations of 698 μg/kg dry weight were measured in sewage sludge and for perfluorohexanesulfonic acid 29.0 μg/kg dry weight were found in biowaste. Looking at the fingerprints of both these matrixes it can be see that long-chain PFAA make up 85.9% of the total concentration in sewage sludge whereas short-chain PFAA only account for 14.1%. In contrast, the trend in biowaste is just the opposite, with 53.2% long-chain and 46.8% short-chain PFAA. These results lead to the conclusion that sewage sludge functions as a sink for long-chain PFAA, and the plants preferentially take up short-chain PFAA from the sludge/soil, as seen by the concentrations found in biowaste. It can be calculated that the total yearly amount of PFAA spread onto agricultural lands amount to 15.3 kg.
