Aufsatz in einer Fachzeitschrift
Bis-3Ferrocenophanes with Central E-E'< Bonds (E, E'=P, SiH): Preparation, Properties, and Thermal Activation
Details zur Publikation
Autor(inn)en: | Isenberg, S.; Weller, S.; Kargin, D.; Valić, S.; Schwederski, B.; Kelemen, Z.; Bruhn, C.; Krekić, K.; Maurer, M.; Feil, C.; Nieger, M.; Gudat, D.; Nyulászi, L.; Pietschnig, R. |
Publikationsjahr: | 2019 |
Zeitschrift: | ChemistryOpen |
Seitenbereich: | 1235-1243 |
Jahrgang/Band : | 8 |
Heftnummer: | 10 |
ISSN: | 2191-1363 |
eISSN: | 2191-1363 |
DOI-Link der Erstveröffentlichung: |
Zusammenfassung, Abstract
A series of bis-[3]ferrocenophanes of the general type Fe(C5H4E')2E-E(E'C5H4)2Fe (E=P, SiH and E'=PtBu, NneoPentyl, NSi(CH3)3) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X-ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.
A series of bis-[3]ferrocenophanes of the general type Fe(C5H4E')2E-E(E'C5H4)2Fe (E=P, SiH and E'=PtBu, NneoPentyl, NSi(CH3)3) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X-ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.
