Journal article
Synthesis and Exfoliation of a New Layered Mesoporous Zr-MOF Comprising Hexa- and Dodecanuclear Clusters as Well as a Small Organic Linker Molecule
Publication Details
Authors: | Backes, C.; Leubner, S.; Bengtsson, V.; Synnatschke, K.; Koch, A.; Gosch, J.; Reinsch, H.; Xu, H.; Zou, X.; Stock, N. |
Publisher: | AMER CHEMICAL SOC |
Publication year: | 2020 |
Journal: | Journal of the American Chemical Society |
Pages range : | 15995-16000 |
Volume number: | 142 |
Issue number: | 37 |
Start page: | 15995 |
End page: | 16000 |
Number of pages: | 6 |
ISSN: | 0002-7863 |
DOI-Link der Erstveröffentlichung: |
Abstract
A new layered mesoporous Zr-MOF of composition [Zr30O20(OH)(26)(OAc)(18)L-18] was synthesized by employing 5-acetamidoisophthalic acid (H2L) using acetic acid as the solvent. The new MOF, denoted as CAU-45, exhibits a honeycomb structure of stacked layers which comprise both hexa- and dodecanucelar zirconium clusters. Its structure was solved from submicrometer-sized crystals by continuous rotation electron diffraction (cRED). Liquid phase exfoliation and size selection were successfully performed on the material.
A new layered mesoporous Zr-MOF of composition [Zr30O20(OH)(26)(OAc)(18)L-18] was synthesized by employing 5-acetamidoisophthalic acid (H2L) using acetic acid as the solvent. The new MOF, denoted as CAU-45, exhibits a honeycomb structure of stacked layers which comprise both hexa- and dodecanucelar zirconium clusters. Its structure was solved from submicrometer-sized crystals by continuous rotation electron diffraction (cRED). Liquid phase exfoliation and size selection were successfully performed on the material.
