Journal article

Directing protonation in [FeFe] hydrogenase active site models by modifications in their second coordination sphere



Publication Details
Authors:
Ezzaher, S.; Gogoll, A.; Bruhn, C.; Ott, S.

Publication year:
2010
Journal:
Chemical Communications
Pages range :
5775-5777
Volume number:
46
Start page:
5775
End page:
5777
ISSN:
1359-7345


Abstract
Subtle changes in the second coordination sphere of [Cl(2)bdtFe(2)-(CO)(4)(Ph2P-CH2-X-CH2-PPh2)] (bdt = benzene-1,2-dithiolate, X = NCH3, NCH2CF3, CH2) that do not influence the electronic character of the Fe-2 center can however direct protonation to three different sites: the N in the bis-phosphane, the Fe-Fe bond or the bdt-S.


Authors/Editors

Last updated on 2022-20-04 at 14:24