Aufsatz in einer Fachzeitschrift
tert-Butyldifluoro(2,4,6-tris-iso-propylphenyl)silane, t-Bu(2,4,6-i-PrC6H2)SiF2.
Details zur Publikation
Autor(inn)en: | Pietschnig, R.; Belaj, F. |
Verlag: | John Wiley & Sons Ltd. |
Publikationsjahr: | 2004 |
Zeitschrift: | Applied Organometallic Chemistry |
Seitenbereich: | 300-301 |
Jahrgang/Band : | 18 |
Erste Seite: | 300 |
Letzte Seite: | 301 |
ISSN: | 0268-2605 |
DOI-Link der Erstveröffentlichung: |
Zusammenfassung, Abstract
Crystals of the title compd. are triclinic, space group P̅1, with a 5.941(2), b 9.743(3), c 17.328(4) Å, α 75.76(2), β 80.35(2), γ 80.40(2)°; Z = 2; R = 0.066 for 2984 reflections. Due to steric congestion within the compd., the geometry at the silicon atom deviates slightly from ideal tetrahedral geometry with an increased C-Si-C angle of 115.97(12)° and an elongated Si-Caryl bond distance. [on SciFinder(R)]
Crystals of the title compd. are triclinic, space group P̅1, with a 5.941(2), b 9.743(3), c 17.328(4) Å, α 75.76(2), β 80.35(2), γ 80.40(2)°; Z = 2; R = 0.066 for 2984 reflections. Due to steric congestion within the compd., the geometry at the silicon atom deviates slightly from ideal tetrahedral geometry with an increased C-Si-C angle of 115.97(12)° and an elongated Si-Caryl bond distance. [on SciFinder(R)]
Schlagwörter
butyl fluoro isopropylphenyl silane prepn crystal structure, mol structure butyl fluoro isopropylphenyl silane
