Journal article
tert-Butyldifluoro(2,4,6-tris-iso-propylphenyl)silane, t-Bu(2,4,6-i-PrC6H2)SiF2.
Publication Details
Authors: | Pietschnig, R.; Belaj, F. |
Publisher: | John Wiley & Sons Ltd. |
Publication year: | 2004 |
Journal: | Applied Organometallic Chemistry |
Pages range : | 300-301 |
Volume number: | 18 |
Start page: | 300 |
End page: | 301 |
ISSN: | 0268-2605 |
DOI-Link der Erstveröffentlichung: |
Abstract
Crystals of the title compd. are triclinic, space group P̅1, with a 5.941(2), b 9.743(3), c 17.328(4) Å, α 75.76(2), β 80.35(2), γ 80.40(2)°; Z = 2; R = 0.066 for 2984 reflections. Due to steric congestion within the compd., the geometry at the silicon atom deviates slightly from ideal tetrahedral geometry with an increased C-Si-C angle of 115.97(12)° and an elongated Si-Caryl bond distance. [on SciFinder(R)]
Crystals of the title compd. are triclinic, space group P̅1, with a 5.941(2), b 9.743(3), c 17.328(4) Å, α 75.76(2), β 80.35(2), γ 80.40(2)°; Z = 2; R = 0.066 for 2984 reflections. Due to steric congestion within the compd., the geometry at the silicon atom deviates slightly from ideal tetrahedral geometry with an increased C-Si-C angle of 115.97(12)° and an elongated Si-Caryl bond distance. [on SciFinder(R)]
Keywords
butyl fluoro isopropylphenyl silane prepn crystal structure, mol structure butyl fluoro isopropylphenyl silane
